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CHEMISTRY OF FIRE RETARDANTS Fire is a leth

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Fire is a lethal force that can easily escape control. In structures, it often starts in the building's furnishings and then ignites the structure itself. One of the keys to fire control, therefore, is to prevent the fire from spreading throughout a building via its contents, usually by depriving the fire of the fuel it needs to grow. It is this premise of flame suppression that underlies most research into flame retardants.

There are several fire types and "hazard situations": nonflaming/smoldering fires, early or small flaming fires, and fully developed large-scale (called post-flashover) fires (The British Plastics Federation, 1990, p. 207). Nonflaming/smoldering fires can start from overheating of vulnerable substances or can be self-sustaining over a long period of time, after which the fire may finally break out into flame. The hazard of toxic gases gradually filling the atmosphere can lead to the incapacitation of anyone in the affected area. The goal of fire retardant developers, therefore, is to ensure that the production of toxic gas is not a dominant result of a materials decomposition.

Fire retardants play a significant role in early or small flaming fires by reducing the chance of flaming ignition and by slowing the rate of fire growth. As with smoldering fires, however, the production of toxic gases is a problem. Considered most effective on the early stages of fire growth, it is unclear the extent to which fire ret

. . .
e basic concept behind hydrated materials is that they work by releasing water during decomposition caused by being exposed to heat, thus dousing the flames. Mg(OH)2, however, is an even more effective flame retardant, especially as a filler in polypropylene. In addition, it "is an effective smoke suppressant . . . and promotes char formation (Society of Plastics Engineers..., 1985, p. 123)." Char formation is an important factor in flame retardants because it "insulates lower layers from imposed heat flux (The British Plastics Federation, 1990, p. 200)." Chlorine and bromine have long been established as effective flame retardants, whether physically incorporated into an organic polymer or as part of the polymer structure itself. As noted above, however, these "halogenated" polymers have been found to produce dangerous levels of smoke and corrosive gases during combustion as well as to form corrosive acids when combined with water, leading to the need to develop fire retardants with less toxic side effects that are just as efficient. Because of this demand for "nontoxic flame- and smoke-suppressant systems for synthetic polymers, certain inorganic tin compounds have been evaluated as fire retardants (The British Plastics
. . .

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Approximate Word count = 1489
Approximate Pages = 6 (250 words per page)

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